volume 48, issue 1, P1-15 2007
DOI: 10.1002/jctb.280480102
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Abstract: The interfacial activities of triisooctylamine, dihexyl sulphide and dodecylmethyl sulphide were studied and used to discuss the mechanism of palladium (IZ) extraction )om acidic chloride solutions by a mixture of dialkyl sulphide with triisooctylamine. The surface excess isotherms were computed and amine association was considered. The extraction occurs probably according to a complex interfacial-bulk mechanism in which the reaction between palladium and protonated amine occurs mainly in the bulk of the aque…

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