The Preparation of Bis(pentamethylcyclopentadienyl)zinc and Bis(trimethylsilylcyclopentadienyl)zinc, and their Molecular Structures Determined by Gas Electron Diffraction.

Blom, Richard; Boersma, J.; Budzelaar, Peter H. M.; Fischer, B.; Haaland, Arne; Volden, Hans V.; Weidlein, Johann; Zingaro, Ralph A.

doi:10.3891/acta.chem.scand.40a-0113

Cited by 76 publications

(65 citation statements)

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“…It is obvious that no reliable data with respect to individual bond distances and angles could be obtained. Gas-phase electron diffraction studies of 59 pointed to a slip sandwich structure also in the gas phase 110 . To overcome the problem of crystallographic disorder during the structural characterization by X-ray crystallography, various substituted cyclopentadienyl compounds, i.e.…”

Section: B Diorganozinc Compounds Containing Multi-hapto Bonded Groupsmentioning

confidence: 97%

Structural Organozinc Chemistry

Jastrzebski

Boersma

Koten

2009

Patai's Chemistry of Functional Groups

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Introduction Organozincates Dialkyl‐ and Diarylzinc Compounds Heteroleptic RZn Y Compounds Organozinc Compounds Containing a Zinc–Transition Metal Bond Conclusions

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Section: B Diorganozinc Compounds Containing Multi-hapto Bonded Groupsmentioning

confidence: 97%

Structural Organozinc Chemistry

Jastrzebski

Boersma

Koten

2009

Patai's Chemistry of Functional Groups

Self Cite

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Introduction Organozincates Dialkyl‐ and Diarylzinc Compounds Heteroleptic RZn Y Compounds Organozinc Compounds Containing a Zinc–Transition Metal Bond Conclusions

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“…Cp* 2 Zn was prepared according to literature methods. [25] = 2968, 2911, 2854, 1580, 1441, 1402, 1383, 1356, 1327, 1292, 1260, 1110, 1062, 1018, 842, 809, 725, 696, 643, 626, 494, 465 cm -1 .…”

Section: Methodsmentioning

confidence: 99%

Direct Carboxylation of Zincocene Cp*₂Zn

et al. 2011

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The reaction of zincocene Cp*2Zn with CO2 proceeds with the formation of [Zn4(μ4‐O)(O2CCp*)6] (1), which was characterized by NMR (1H, 13C) and IR spectroscopy as well as by elemental analysis and single‐crystal X‐ray diffraction. The solid‐state structure of 1 is comparable to that previously observed for basic zinc acetate. In contrast to many previously reported CO2 activation reactions, the formation of 1 occurred without the use of any additional transmetalation catalyst.

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“…Solvents were dried by standard procedures and degassed prior to use. [ZnCp* 2 ] [15] and [Zn 2 Cp* 2 ]…”

Section: Methodsmentioning

confidence: 99%