volume 5, issue 2, P237-240 2014
DOI: 10.5155/eurjchem.5.2.237-240.981
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Abstract: KEYWORDSThe kinetics of oxidation of 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol by dihydroxydiperiodato nickelate(IV) (DPN) had been studied spectrophotometrically in alkaline medium in the temperature range of 293.2 to 313.2 K. The reaction rate showed first order dependence on DPN, 2-(2-methoxyethoxy)-ethanol and 2-(2-ethoxyethoxy)-ethanol. It was found that the pseudo-first-order rate constant kobs increased with an increase in concentration of OH -and a decrease in concentration of IO4 -. …

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