Commercially,
lithium metal batteries are still limited by the
growth of lithium dendrites and excessive consumption of electrolyte.
The lithium–sulfur battery has the advantages of high energy
density and low material cost. It is considered to be one of the most
promising energy storage technology batteries. Although it has developed
rapidly in recent decades, there is still a crucial problem: the shuttle
of lithium polysulfide (LiPSs). To solve this critical problem, the
Ni–VO2 nanoflower structure is designed to strongly
adsorb LiPSs, lower the Li2S decomposition barrier, accelerate
the effective discharge in the reaction process, and improve the Coulomb
efficiency. Particularly, the Ni–VO2 coating layer
demonstrated a high initial discharge capacity of 853 mAh g–1 at 1 C and retained a stable cycling performance with a reversible
capacity of 632 mAh g–1 over 1000 cycles (capacity
decay of 0.002% per cycle). Even under extreme conditions of 0 and
60 °C, the capacities of 700 and 920 mAh g–1 are maintained, respectively. Such excellent wide temperature performance
and cycle stability reveal its good potential for use in advanced
Li–S batteries.