Porous sol-gel silica films doped with nanocrystalline NiO particles for gas sensing applications Buso, D.; Guglielmi, M.; Martucci, A.; Cantalini, C.; Post, M. L.; Haché, A.Contact us / Contactez nous: nparc.cisti@nrc-cnrc.gc.ca. Abstract A reliable sol gel route to synthesize NiO doped SiO 2 films with different NiO content is here described. The films showed detectable and reversible changes in both optical and electrical properties when exposed to some reducing/oxidizing gaseous species at temperatures in the 250• C-350 • C range. A functional characterization protocol has been designed and some of the sensing properties of the materials have been investigated for detecting NO 2 , CH 4 , CO and H 2 . An optical transmittance increase up to 2% has been detected for 1% CO in dry air atmospheres, while relative resistance response (R R = R gas /R air ) values up to 4.97 for 850 ppm H 2 /air mixtures have been registered for conductometric gas sensing. Films at all NiO molar concentrations in the 10% NiO -40% range showed an optical response to the target gas, while only 30% and 40% NiO films provided a detectable gas induced resistance change.