The influence of the phosphorus-based flame retardant on the flame retardancy of the epoxy resins

Zhang, Wenchao; He, Xiangdong; Song, Tinglu; Jiao, Qingze

doi:10.1016/j.polymdegradstab.2014.07.023

Cited by 150 publications

(74 citation statements)

References 33 publications

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“…In recent years, most of the researches tend to find halogen-free flame retardant solutions. Among the halogen-free systems, epoxy resin modified by phosphorus is considered as a promising alternative to halogenated flame retardants due to its low toxicity and high efficiency [9,10,14].…”

Section: Introductionmentioning

confidence: 99%

Synthesis of a novel PEPA-substituted polyphosphoramide with high char residues and its performance as an intumescent flame retardant for epoxy resins

Zhao

Liu

Peng

et al. 2015

Polymer Degradation and Stability

135

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Section: Introductionmentioning

confidence: 99%

Synthesis of a novel PEPA-substituted polyphosphoramide with high char residues and its performance as an intumescent flame retardant for epoxy resins

Zhao

Liu

Peng

et al. 2015

Polymer Degradation and Stability

135

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“…This result may be caused by the catalytic degradation effect of NiAl and CoAl-LDH for PS matrix during combustion [44,45]. The cone T 0.1 and T 0.5 were temperatures at which 10% weight loss and 50% weight loss occurred; char (%) was determined from remaining char weight at 600 8C.…”

Section: Flame-retardation Propertiesmentioning

confidence: 99%

Preparation and flame retardancy of polystyrene nanocomposites based on layered double hydroxides

Han

Shen

et al. 2015

Polym. Compos.

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Various layered double hydroxides (LDHs), including MgAl, CoAl, NiAl, and ZnAl-LDHs, were synthesized and modified using sodium dodecyl benzene sulfonate. Nonhalogen flame-retardant PS/LDHs nanocomposites were prepared via melt mixing method. The structure of PS/LDHs nanocomposites was investigated by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) pattern technique, and scanning electronic microscope. Results from XRD indicated that intercalated/exfoliated structure was achieved in the polystyrene matrix. Dynamic mechanical thermal analysis suggested that the storage modulus and T g for the PS/LDHs nanocomposites was efficiently improved. Thermal and flammability properties of PS nanocomposites were investigated using thermogravimetry and cone calorimetry. Thermal analysis was evaluated and the prepared nanocomposites showed slightly lower thermal stability probably due to the presence of LDH, which starts to decompose at a lower temperature. Compared with neat PS, the peak heat release rate of PS/MgAl and PS/ZnAl-LDHs nanocomposites filled with 5 wt% LDHs is reduced by 7 and 12%, respectively. Among all LDHs, MgAl, and ZnAl-LDHs had a better smoke suppression effect with a reduction of peak smoke production rate and CO release rate of 37 and 44%, respectively. POLYM. COMPOS., 00:000-000, 2015.

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“…Therefore, mesogenic epoxy shows excellent thermal conductivity, mechanical properties and thermal stability [8e11]. However, mesogenic epoxy is desperate flammable, which can cause fire hazard and limit its application in modern electronics device [12,13].…”

Section: Introductionmentioning

confidence: 99%

Anisotropic thermal conductivity and flame retardancy of nanocomposite based on mesogenic epoxy and reduced graphene oxide bulk

Luo

Guo

et al. 2016

Composites Science and Technology

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The influence of the phosphorus-based flame retardant on the flame retardancy of the epoxy resins

Cited by 150 publications

References 33 publications

Synthesis of a novel PEPA-substituted polyphosphoramide with high char residues and its performance as an intumescent flame retardant for epoxy resins

Synthesis of a novel PEPA-substituted polyphosphoramide with high char residues and its performance as an intumescent flame retardant for epoxy resins

Preparation and flame retardancy of polystyrene nanocomposites based on layered double hydroxides

Anisotropic thermal conductivity and flame retardancy of nanocomposite based on mesogenic epoxy and reduced graphene oxide bulk

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