2017
DOI: 10.1016/j.electacta.2017.03.020
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The impact of high-frequency-high-current perturbations on film formation at the negative electrode-electrolyte interface

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Cited by 36 publications
(21 citation statements)
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“…The Butler-Volmer equation provides expression that relates current density to applied potential [33,34]. Since anodic overpotential of 50mV and beyond were utilised in this work, the anodic exponential term predominates [35,33,36] which implies that measured current was solely a measure of applied anodic potential [35] that caused metallic dissolution.…”
Section: Application Of Faraday's Law Of Electrolysis To Potentiostatmentioning
confidence: 99%
“…The Butler-Volmer equation provides expression that relates current density to applied potential [33,34]. Since anodic overpotential of 50mV and beyond were utilised in this work, the anodic exponential term predominates [35,33,36] which implies that measured current was solely a measure of applied anodic potential [35] that caused metallic dissolution.…”
Section: Application Of Faraday's Law Of Electrolysis To Potentiostatmentioning
confidence: 99%
“…For the case of extremely high frequencies, the AV oscillation almost gives no rise to the corrosion potential or passive range of polarization curves. It is highly possible that the AV signals only work on electric double layer to charge and discharge when the AV frequency increases up to an extremely high level . Typically, the aspect of the frequency lower than 50 Hz is also considered in this work as shown in Figure .…”
Section: Resultsmentioning
confidence: 99%
“…In [13] cells were charged with frequencies of 0Hz, 10Hz, 55Hz, 254Hz and 14.8kHz. Here an increase in 3 percentage points of capacity fade was observed at the cells charged with the highest frequency.…”
Section: A Charging Frequency and F Zminmentioning
confidence: 99%
“…], [1], [7]- [10], reduced charging time [1], [8], [10], [11], and decreased battery aging [8], [12]- [14], among others. However, other studies have also found negligible or even negative effects [13], [15]- [17]. Therefore, the goal and contribution of this paper are to investigate and review what the effects of PC are on lithiumbased batteries.…”
Section: Introductionmentioning
confidence: 98%