The Hizeh‐Jan Kaolin Deposit of NW Iran: the Tetrad Effect in REE Distribution Patterns

Abstract

The Hizeh‐Jan kaolin deposit (northwest of Varzeghan, East‐Azarbaidjan Province, NW Iran) is a product of the alteration of Eocene andesitic rocks. Based on mineralogical examinations, kaolinite, quartz, smectite, pyrophyllite, muscovite‐illite, alunite, calcite, diaspore, goethite and hematite are the most abundant mineral phases in this deposit. The geochemical indicators, such as Y/Ho and Zr/Hf, indicate the non‐CHARAC (non‐Charge‐radius control) behavior of these pairs, which are likely to be due to the occurrence of the tetrad effect phenomenon in this deposit. Simultaneous concave and convex shapes in the chondrite‐normalized REE distribution patterns are a remarkable feature of the kaolin samples. Bivariate diagrams of the size of the third tetrad effect (T3) versus geochemical parameters such as Y/Ho, Nb/Ta and Zr/Hf ratios display two distinct populations for the kaolin samples. The first population is characterized by high T3 values (>0.13), which are near or on the fault zone. The second population is characterized by low T3 values (<0.13), and are farther from the fault zone. The obtained results from the geochemical data have furnished compelling evidence that fluid‐rock interaction, overprint of hypogene processes by supergene ones, and structural control, are key controlling factors for the occurrence of tetrad effects in REE distribution patterns in the Hizeh‐Jan kaolin deposit.

Application of lanthanides tetrad effect as a geochemical indicator to identify fluorite generations: A case study from the Laal-Kan fluorite deposit, NW Iran

“…Based on the recent works, the form of tetrad effect-bearing normalized REE curves can be categorized into four groups [Abedini and Rezaei Azizi, 2019, Abedini et al, 2019b, Feng et al, 2014, Minamim et al, 1998, Nardi et al, 2012: (1) concave or W-type indicative for low temperature deposits, (2) convex or M-type generally occur in magmatic or related systems, (3) conjugate convex-concave or W-M-type and finally (4) zigzag pattern, which can be related to incomplete occurrence of tetrad effect. Previous studies have proposed some quantum mechanical based mechanisms for the occurrence of tetrad effect such as nephelauxetic ratios, the spin energy for coupling, electron configuration of lanthanides and Gibbs free energy [Jorgensen, 1970, Kawabe et al, 1999, Masuda et al, 1994, Nugent, 1970.…”

Pologivskiy Kaolin Deposit: Geology, Mineral and Chemical Composition, Technological Properties

“…The data processing of the world geological community in relation to kaolin deposits in Russian Federation , Nigeria , China , Iran Abedini, Rezaei Azizi, 2019), Ethiopia , Algeria , South Africa , Malaysia , Cameroon (Nzeukou Nzeugang et al, 2018), Turkey , Egypt . ), Japan showed that the kaolin ores of the Pologivskiy deposit have higher geological and economic indicators, the study of which is a further goal for the authors research.…”