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Cited by 15 publications
(14 citation statements)
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“…First we synthesized layered Mn oxides with K(I) between the layers and then replaced them by Ca(II), Mg(II), La(III) or Ni(II). Using the strategy, very similar oxides only with different ions between the layers could be obtained [61]. We found that in the presence of cations such as Ca(II), K(I), Mg(II), La(III) and Ni(II) between the layers very similar activity to Mn oxides could be obtained, but no ion is specific for water oxidation at least in the presence of Ce(IV) as an oxidant [61].…”
Section: The Role Of Redox-inert Ions In the Layered Mn Oxidesmentioning
confidence: 96%
See 2 more Smart Citations
“…First we synthesized layered Mn oxides with K(I) between the layers and then replaced them by Ca(II), Mg(II), La(III) or Ni(II). Using the strategy, very similar oxides only with different ions between the layers could be obtained [61]. We found that in the presence of cations such as Ca(II), K(I), Mg(II), La(III) and Ni(II) between the layers very similar activity to Mn oxides could be obtained, but no ion is specific for water oxidation at least in the presence of Ce(IV) as an oxidant [61].…”
Section: The Role Of Redox-inert Ions In the Layered Mn Oxidesmentioning
confidence: 96%
“…Thus, to compare the water-oxidizing activities of different Mn oxides all these factors should be carefully analyzed. Recently, we used a new strategy to find the effect of different ions between the layers of Mn oxides on water oxidation [61]. First we synthesized layered Mn oxides with K(I) between the layers and then replaced them by Ca(II), Mg(II), La(III) or Ni(II).…”
Section: The Role Of Redox-inert Ions In the Layered Mn Oxidesmentioning
confidence: 99%
See 1 more Smart Citation
“…On the other hand, Nature uses a manganese‐calcium oxide‐based cluster as an efficient oxygen‐evolving catalyst, [6] which is of great interest as a model for designing artificial oxygen‐evolving catalysts [7] . In using Mn oxides as water‐oxidizing catalysts, the challenges are finding the mechanism of OER at an atomic level, the rate‐determining step, improving the synthetic procedure for Mn oxide formation, understanding the mechanism of Mn‐oxide formation, finding the roles of Mn ions with different oxidation states (II‐VII) in the meanwhile of OER, the conversion of numerous Mn oxides over OER, detection of the active intermediate during OER, and the roles of Mn III in OER [8–25] …”
Section: Introductionmentioning
confidence: 99%
“…Nanolayered Mn–A (A: metal cations) oxides were investigated for OER [14] . The described activity followed the overall trend Ca 2+ >Sr 2+ >Mg 2+ >Na + ,K + ; [15] however, the exact role of the cations in the activity of OER is still unidentified [16] …”
Section: Introductionmentioning
confidence: 99%