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Cited by 196 publications
(170 citation statements)
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References 374 publications
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“…Several metal complexes with the tpea ligand have been synthesized and they usually have formed four or five coordinated complexes. 11 However, two factors attracted us to choose the ligand as a candidate for the octahedral Ru(III) model complex: strong tendencies (i) toward the six-coordination of Ru ions and (ii) the formation of six-membered chelate rings with near perpendicular bite angles of tpea upon coordination. In this study, we have used the tpea ligand to synthesize a new model octahedral Ru(III) complex and investigated its structure and physiological reactivity.…”
Section: -10mentioning
confidence: 99%
“…Several metal complexes with the tpea ligand have been synthesized and they usually have formed four or five coordinated complexes. 11 However, two factors attracted us to choose the ligand as a candidate for the octahedral Ru(III) model complex: strong tendencies (i) toward the six-coordination of Ru ions and (ii) the formation of six-membered chelate rings with near perpendicular bite angles of tpea upon coordination. In this study, we have used the tpea ligand to synthesize a new model octahedral Ru(III) complex and investigated its structure and physiological reactivity.…”
Section: -10mentioning
confidence: 99%
“…Other studies have illustrated how tripodal (N-heterocyclic alkyl)amine ligand design influences the geometry of the complexes and the internal exchange processes between isomers. [3,4] Gayathri et al [5,6] prepared a series of cyclometallated rhodium complexes with 1,3-bis(benzimidazolyl)benzene. The conventional 13 C NMR experiment takes longer time to detect the cyclometallated carbon because of sensitivity problem and also due to poor solubility of metal complexes in the desired solvents.…”
Section: Introductionmentioning
confidence: 99%
“…These initial macrocyclic systems provided an important impact on supramolecular chemistry and in the understanding of naturally occurring macrocycles such as ionophores, hemes, and porphyrins. Later on, the research work pioneered by Donald Cram on macrocyclic cyclophanes, spherands, and carcerands, 10 and the great contribution from Jean-Marie…”
Section: Figurementioning
confidence: 99%
“…9 Then, bis(amino amides) 1 and 2 were subjected to a reductive amination process with benzaldehyde in methanol, affording the ligands 3 and 4 in good yields. 10 The selection of the central spacer containing three methylene groups was based on the results previously obtained with related ligands, showing that this spacer is very well suited to favour the formation of strong 1:1 metal complexes with the bisdeprotonated ligand.…”
Section: Synthesis Characterization and Acid-base Properties Of The mentioning
confidence: 99%
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