Abstract:A novel bimetallic 4f-3d metal-isonicotinic acid inorganic-organic hybrid complex [{Eu(NC 5 H 4 COOH) 3 (H 2 O) 2 }(1.5ZnCl 4 )·(2H 2 O)] n (1) was synthesized via a hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in the space group C2/c of the monoclinic system with eight formula units in a cell: a = 23.878 (8) Å, b = 20.573(6) Å, c = 15.358(5) Å, β = 127.276(5)°, V = 6003(3) Å 3 ,C 18 H 23 Cl 6 EuN 3 O 10 Zn 1.5 , M r = 904.11 g/mol, ρ = 2.001 … Show more
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