Synthesis of Sulfur‐Containing Polymers Through Multicomponent Polymerizations

Huang, Yuzhang; Hu, Rongrong; Tang, Ben Zhong

doi:10.1002/9783527823819.ch1

Cited by 3 publications

(3 citation statements)

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“…Sulfur‐containing polymers that featured numerous fascinating merits such as thermal stability, high refractivity, metal coordination ability, remarkable dielectrical and electrochemical properties have been found great potential applications as optical and optoelectronic materials. [ 38‐41 ] As a result, the synthesis of sulfur‐containing polymers has drawn increasing attentions from the academic and industrial communities. A precursive attempt to prepare poly(enonsulfide)s with good mechanical and thermal performance by nucleophilic addition polymerization of activated dipropynones with aromatic dithiols was reported by Bass and coworkers in 1987 (Scheme 3a).…”

Section: Polymerization Of Mono‐activated Internal Alkynesmentioning

confidence: 99%

Activated Internal Alkyne‐Based Polymerization^†

Wang

et al. 2022

Chin. J. Chem.

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As an emerging and efficient polymerization methodology, activated internal alkyne-based polymerization has been considered as a powerful tool for the construction of polymers with diverse architectures and versatile functions. This review focuses on the recent progresses in the polymerization using mono-activated, di-activated, in-situ generated, ring-strained ethynyl groups as substrates, coupling with post-modification on premade polymers containing activated internal ethynyl moieties. Representative examples are used to illustrate the fundamental design strategy, the development of polymerization and post-functionalization, along with the properties and potential applications of the prepared polymers. Moreover, the challenges and perspectives in terms of new-type active alkynes, green polymerization methodology, tailored regio-/stereoselectivity modulation, and potentially expanded application in this area are also discussed.

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Section: Polymerization Of Mono‐activated Internal Alkynesmentioning

confidence: 99%

Activated Internal Alkyne‐Based Polymerization^†

Wang

et al. 2022

Chin. J. Chem.

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“…21 Thioamides, characterized by the presence of the -C(]S) NH-functional group, have been employed as indispensable building blocks in the synthesis of bioactive compounds, 22,23 pharmaceutical agents, [24][25][26] agrochemicals, 27 and functional materials with tailored properties. 28 Among the myriad of various traditional synthetic methods reported in the literature, [29][30][31][32][33][34][35][36][37][38][39] one of the most efficient methods for thioamide synthesis is the Willgerodt-Kindler (WK) reaction, comprising the three-component condensation of a carbonyl compound, a sulfur reagent, and an amine (primary or secondary) in one pot. 40,41 The reported protocols produce good results in many cases.…”

Section: Introductionmentioning

confidence: 99%

Green synthesis of thioamide derivatives in an environmentally benign deep eutectic solvent (DES)

Mandal,

Jain,

Panda

2024

RSC Sustain.

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“…7,8 These sulfur-containing polymers are commonly produced using chemically modified monomers for polyaddition or polycondensation, or by directly modifying the synthetic polymers. 1,9 In recent years, efficient methods that employ elemental sulfur as a reaction medium and comonomer have been developed to produce chemically stable and processable sulfur copolymers. 8,10–12 Among the synthesized sulfur-containing polymers, thiacyclic polymers are the most attractive, which have found critical applications in the fields of organic electronics, batteries, and so on ( e.g.…”

Section: Introductionmentioning

confidence: 99%