Reactions between Z-XCH=CHX where X = Cl,
CF3, or CN and
produce Mo(N-t-Bu)(CHX)(OHIPT)Cl(PPh2Me) complexes.
Addition of 2,2’-bipyridyl (Bipy) yields
Mo(N-t-Bu)(CHX)(OHIPT)Cl(Bipy) complexes, which could be
isolated and structurally characterized. The reaction between
and Z-ClCH=CHCl in the presence of Bipy produces a mixture that
contains both Mo(N-t-Bu)(CHCl)(OH…
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