volume 37, issue 11, P1641-1644 2018
DOI: 10.1021/acs.organomet.8b00168
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Abstract: Reactions between Z-XCH=CHX where X = Cl, CF3, or CN and Mo(N-t-Bu)(CH-t-Bu)(OHIPT)Cl(PPh2Me) (OHIPT = O-2,6-(2,4,6-i-Pr3C6H2)2C6H3) produce Mo(N-t-Bu)(CHX)(OHIPT)Cl(PPh2Me) complexes. Addition of 2,2’-bipyridyl (Bipy) yields Mo(N-t-Bu)(CHX)(OHIPT)Cl(Bipy) complexes, which could be isolated and structurally characterized. The reaction between Mo(N-t-Bu)(CH-t-Bu)(OHMT)Cl(PPh2Me) (OHMT = O-2,6-(2,4,6-Me3C6H2)2C6H3) and Z-ClCH=CHCl in the presence of Bipy produces a mixture that contains both Mo(N-t-Bu)(CHCl)(OH…

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