Synthesis of hierarchical porous BCN using ternary deep eutectic solvent as precursor and template for aerobic oxidative desulfurization

A current overview of the oxidative desulfurization of fuels utilizing heat and solar light: from materials design to catalysis for clean energy

“…Wei et al also reported the application of B-C 3 N 4 in the ODS of model diesel, but their B-C 3 N 4 was fabricated from a ternary deep eutectic solvent under calcination and spinodal decomposition. 213 As expected, B-C 3 N 4 required only 125 1C to achieve 98.4% DBT removal with O 2 due to the amelioration of reduction potential in the parent boron nitride that could be observed from the cyclic voltammetry curves (Fig. 18i).…”

High‐performance adsorptive desulfurization by ternary hybrid boron carbon nitride aerogel

“…It indicates that the BN domain in BCN‐2.5 has more electrons than that in BCN‐1. It has been well‐established that the structure of BCN would be more stable if a carbon atom substitutes the boron lattices near the edge 52,53 . Based on the aforementioned observations, it is reasonably inferred that part of B atoms are replaced by carbon atom in the BCN aerogels constructed here, which should be favorable to enhancing the interaction between active sites of BCN and S molecular in aerogels, thereby promoting the adsorptive desulfurization performances of BCN aerogels.…”

Deep Eutectic Solvents and Multicomponent Reactions: Two Convergent Items to Green Chemistry Strategies

“…All this gives rise to a wide range of possibilities in the synthesis of materials assisted by DESs. Some recent publications have been done, for example, in the synthesis of nanoparticles (NPs),[ 59 , 88 , 89 , 90 ] MOFs (organo‐metallic structures)[ 91 , 92 ] and structured porosity carbons,[ 93 , 94 ] DESs contribute to supramolecular organization many new materials based on the formation of hydrogen bridges between the reactions components, providing a proper environment that helps to control shapes and sizes, stabilizing agents throughout the process, etc. which is essential for the production of materials with different physicochemical and functional properties.…”