Synthesis of Convertible {PO4[WO3$$\rightleftharpoons$$ W(O)2(O2)]4}-DMA16 in SBA-15 Nanochannels and Its Catalytic Oxidation Activity

Jin, Manman; Guo, Zhaobing; Lv, Zhiguo

doi:10.1007/s10562-019-02761-3

Cited by 7 publications

(1 citation statement)

References 41 publications

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“…Therefore, the Venturello structure contains already active peroxo groups that can easily promote sulfur oxidation. In fact, the Venturello peroxotungstate, PW 4 , has been successfully used as a highly active catalyst in different oxidative reactions [15,[24][25][26][27][28][29]. However, most of these studies use the Venturello compound as a homogeneous catalyst, which is difficult to recover and reuse [30].…”

Section: Introductionmentioning

confidence: 99%

An Effective Hybrid Heterogeneous Catalyst to Desulfurize Diesel: Peroxotungstate@Metal–Organic Framework

et al. 2020

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A peroxotungstate composite comprising the chromium terephthalate metal–organic framework MIL-101(Cr) and the Venturello peroxotungstate [PO4{WO(O2)2}4]3− (PW4) has been prepared by the impregnation method. The PW4@MIL-101(Cr) composite presents high catalytic efficiency for oxidative desulfurization of a multicomponent model diesel containing the most refractory sulfur compounds present in real fuels (2000 ppm of total S). The catalytic performance of this heterogeneous catalyst is similar to the corresponding homogeneous PW4 active center. Desulfurization efficiency of 99.7% was achieved after only 40 min at 70 °C using H2O2 as an oxidant and an ionic liquid as an extraction solvent ([BMIM]PF6, 2:1 model diesel/[BMIM]PF6). High recycling and reusing capacity was also found for PW4@MIL-101(Cr), maintaining its activity for consecutive oxidative desulfurization cycles. A comparison of the catalytic performance of this peroxotungstate composite with others previously reported tungstate@MIL-101(Cr) catalysts indicates that the presence of active oxygen atoms from the peroxo groups promotes a higher oxidative catalytic efficiency in a shorter reaction time.

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