Synthesis, characterization and structure of a diaqua lanthanum bimalonate malonate monohydrate

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

“…These absorptions confirmed the formation of complexes as they were not observed in the ligand spectra. The spectral results are in agreement with the reported literature (Marrot and Trombe, 1994; Doreswamy et al, 2003; Chrysomallidou et al, 2010; Mathew et al, 2012).…”

“…The structure of the compound does not match with any of the earlier reported structures of Ln 3+ complexes involving the hydrogen malonate ligand (Wenmei et al, 1992; Marrot and Trombe, 1994; Delgado et al, 2016).…”

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

“…These absorptions confirmed the formation of complexes as they were not observed in the ligand spectra. The spectral results are in agreement with the reported literature (Marrot and Trombe, 1994; Doreswamy et al, 2003; Chrysomallidou et al, 2010; Mathew et al, 2012).…”

“…The structure of the compound does not match with any of the earlier reported structures of Ln 3+ complexes involving the hydrogen malonate ligand (Wenmei et al, 1992; Marrot and Trombe, 1994; Delgado et al, 2016).…”

Two- and Three-Dimensional Networks of Gadolinium(III) with Dicarboxylate Ligands: Synthesis, Crystal Structure, and Magnetic Properties

“…In the case of Chart b, the Gd(1d 1 )O(3d 1 )C(5d 1 )O(6d 1 )Gd(2d 1 )O(6)C(5)O(3)Gd(1) motif has the boat conformation and the value of the dihedral angle between the O(3d 1 )C(5d 1 )O(6d 1 ) and O(6)C(5)O(3) carboxylate planes is 130.20(1)°. The average C−O bond distances and O−C−O bond angles for the malonate ligands of parts a [1.2615(17) Å and 124.2(9)°], b [1.262(11) Å and 123.7(9)°], and c [1.253(11) Å and 120.8(9)°] in Chart agree well with those previously reported for malonate-containing lanthanide complexes. ,,− ,,,, ,,,,

1 Coordination Modes of the Malonate Ligand in the Structures 1 and 2

…”

Polymeric tetraaquatris(malonato)dilanthanum(III) monohydrate

“…The distances and angles in the two independent ligands and the LaÐO bond lengths agree with those found in analogous compounds (Marrot & Trombe, 1993, 1994, with one LaÐO bond being considerably longer. This kind of distance seems to be rather typical of the chelating carboxylate group (Hansson, 1973a,b).…”

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

“…These absorptions confirmed the formation of complexes as they were not observed in the ligand spectra. The spectral results are in agreement with the reported literature (Marrot and Trombe, 1994; Doreswamy et al, 2003; Chrysomallidou et al, 2010; Mathew et al, 2012).…”

“…The structure of the compound does not match with any of the earlier reported structures of Ln 3+ complexes involving the hydrogen malonate ligand (Wenmei et al, 1992; Marrot and Trombe, 1994; Delgado et al, 2016).…”

Two- and Three-Dimensional Networks of Gadolinium(III) with Dicarboxylate Ligands: Synthesis, Crystal Structure, and Magnetic Properties

“…In the case of Chart b, the Gd(1d 1 )O(3d 1 )C(5d 1 )O(6d 1 )Gd(2d 1 )O(6)C(5)O(3)Gd(1) motif has the boat conformation and the value of the dihedral angle between the O(3d 1 )C(5d 1 )O(6d 1 ) and O(6)C(5)O(3) carboxylate planes is 130.20(1)°. The average C−O bond distances and O−C−O bond angles for the malonate ligands of parts a [1.2615(17) Å and 124.2(9)°], b [1.262(11) Å and 123.7(9)°], and c [1.253(11) Å and 120.8(9)°] in Chart agree well with those previously reported for malonate-containing lanthanide complexes. ,,− ,,,, ,,,,

1 Coordination Modes of the Malonate Ligand in the Structures 1 and 2

…”

Polymeric tetraaquatris(malonato)dilanthanum(III) monohydrate

“…The distances and angles in the two independent ligands and the LaÐO bond lengths agree with those found in analogous compounds (Marrot & Trombe, 1993, 1994, with one LaÐO bond being considerably longer. This kind of distance seems to be rather typical of the chelating carboxylate group (Hansson, 1973a,b).…”

Synthesis, Thermal, Structural Analyses, and Photoluminescent Properties of a New Family of Malonate-Containing Lanthanide(III) Coordination Polymers

“…These absorptions confirmed the formation of complexes as they were not observed in the ligand spectra. The spectral results are in agreement with the reported literature (Marrot and Trombe, 1994; Doreswamy et al, 2003; Chrysomallidou et al, 2010; Mathew et al, 2012).…”

“…The structure of the compound does not match with any of the earlier reported structures of Ln 3+ complexes involving the hydrogen malonate ligand (Wenmei et al, 1992; Marrot and Trombe, 1994; Delgado et al, 2016).…”

Two- and Three-Dimensional Networks of Gadolinium(III) with Dicarboxylate Ligands: Synthesis, Crystal Structure, and Magnetic Properties

“…In the case of Chart b, the Gd(1d 1 )O(3d 1 )C(5d 1 )O(6d 1 )Gd(2d 1 )O(6)C(5)O(3)Gd(1) motif has the boat conformation and the value of the dihedral angle between the O(3d 1 )C(5d 1 )O(6d 1 ) and O(6)C(5)O(3) carboxylate planes is 130.20(1)°. The average C−O bond distances and O−C−O bond angles for the malonate ligands of parts a [1.2615(17) Å and 124.2(9)°], b [1.262(11) Å and 123.7(9)°], and c [1.253(11) Å and 120.8(9)°] in Chart agree well with those previously reported for malonate-containing lanthanide complexes. ,,− ,,,, ,,,,

1 Coordination Modes of the Malonate Ligand in the Structures 1 and 2

…”

Polymeric tetraaquatris(malonato)dilanthanum(III) monohydrate

“…The distances and angles in the two independent ligands and the LaÐO bond lengths agree with those found in analogous compounds (Marrot & Trombe, 1993, 1994, with one LaÐO bond being considerably longer. This kind of distance seems to be rather typical of the chelating carboxylate group (Hansson, 1973a,b).…”