2020
DOI: 10.1021/jacs.0c07146
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Abstract: Polyoxometalate molybdenum blue (MB) complexes typically exist as discrete multianionic clusters and are composed of repeating Mo building units. MB wheels such as {Mo 176 } and {Mo 154 } are made from pentagon-centered {Mo 8 } building blocks joined by equal number of {Mo 1 } units as loin, and {Mo 2 } dimer units as skirt along the ring edge, with the ring sizes of the MB wheels modulated by the {Mo 2 } units. Herein we report a new class of contracted lanthanide-doped MB structures that have replaced all th… Show more

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Cited by 42 publications
(49 citation statements)
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“…Since then, POMs have been synthesized with elements throughout the periodic table, thus we can find examples with lanthanides, actinides, and other transition metals . This chemical variety has been accompanied by a broad range of topologies: molybdenum blue wheels, , keplerates, , and polyperoxouranates. , Metal-oxo compounds also present different applications in relevant fields such as biochemistry, catalysis, and nuclear reprocessing. , …”
Section: Introductionmentioning
confidence: 99%
“…Since then, POMs have been synthesized with elements throughout the periodic table, thus we can find examples with lanthanides, actinides, and other transition metals . This chemical variety has been accompanied by a broad range of topologies: molybdenum blue wheels, , keplerates, , and polyperoxouranates. , Metal-oxo compounds also present different applications in relevant fields such as biochemistry, catalysis, and nuclear reprocessing. , …”
Section: Introductionmentioning
confidence: 99%
“…15,16 Polyoxometalates (POMs) are a kind of molecularly well-defined metal-oxide clusters, which have been widely used to prepare hybrid materials due to their high acid strength, dispersity, and thermal stability. [17][18][19][20] The main synthetic strategies of POMs included conventional synthesis and hydrothermal method. 21,22 In the past few years, POMs compounds have made excellent achievements in the field of proton conductivity.…”
Section: Introductionmentioning
confidence: 99%
“…Chemists are always amazed by the marvelous hierarchical structures in nature, where multiple basic building units (e.g., proteins or nucleotides) stepwise self-assemble into complex macromolecules with emergent functions arising from the collective behaviors of aggregated components. , Over the past decades, metal-directed self-assembly has become a powerful approach in designing sophisticated functional supramolecular architectures. In virtue of the coordination behavior (i.e., coordination numbers and geometries) analogous to that of metal ions, anion-templated synthesis or anion-directed self-assembly has also been very successful in the design of unique supramolecular structures. However, the properties and functions of those artificial assemblies are mainly derived from their primary and secondary structures. While many metallasupramolecular complexes are positively charged, the existence of counteranions is often overlooked due to their strong solvation in solution or high disorder in the solid state.…”
Section: Introductionmentioning
confidence: 99%