Darya M. Sedlovets, Maksim V. Shuvalov, Yury V. Vishnevskiy, Vladimir T. Volkov, Igor I. Khodos, Oleg V. Trofimov, Vitaly I. Korepanov
ABSTRACT:We propose an experimental approach, by which thin films of copper polyphthalocyanine (CuPPC) can be directly synthesized in a chemical vapor deposition (CVD) set-up at mild temperature (420 °C). High polymerization degree and high crystallinity of the films was confirmed by TEM, FTIR and UV-VIS studies; the stacking structure of CuPPC layers was determined, inter-layer spacing was estimated from XRD and TEM electron-diffraction. Quantum-chemical study performed providing support for experimental str…
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