2016
DOI: 10.1021/acs.inorgchem.6b00745 View full text |Buy / Rent full text
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Abstract: The reaction of R2Zn (R = Et, (t)Bu) with 3,5-diphenylpyrazole results in the formation of three structurally diverse alkylzinc pyrazolates: a novel dinuclear tetrahydrofuran solvate, an unprecedented trimeric structure, and a spiro trinuclear aggregate. Structural analysis of the resulting complexes provides a new look at the aggregation and stabilization of alkylzinc species.

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