Synthesis and structural characterization of the benzimidazolate-bridged binuclear copper(II) complex with N,N′-bis(carboxymethyl)glycine

Homodinuclear RhI and IrI Complexes Derived from Imidazolium‐Benzimidazolates

“…The latter complex contains a functionalised bridging k 1 N : k 1 N benzimidazolato ligand without additional chelation, which is rarely observed in the chemistry of benzimidazole-based ligands. [11] The structure of these complexes in solution is essentially identical to that in the solid state according to an NMR spectroscopic analysis. The two COD ligands present in [RhCl (COD){Rh(μ-1'a)(COD)}] and [RhCl(COD){Rh(μ-1'b)(COD)}] give rise to eight 13 C NMR signals for the CH 2 units in each case.…”

Homodinuclear RhI and IrI Complexes Derived from Imidazolium‐Benzimidazolates

“…The latter complex contains a functionalised bridging k 1 N : k 1 N benzimidazolato ligand without additional chelation, which is rarely observed in the chemistry of benzimidazole-based ligands. [11] The structure of these complexes in solution is essentially identical to that in the solid state according to an NMR spectroscopic analysis. The two COD ligands present in [RhCl (COD){Rh(μ-1'a)(COD)}] and [RhCl(COD){Rh(μ-1'b)(COD)}] give rise to eight 13 C NMR signals for the CH 2 units in each case.…”

Reversible Coordinative Bonds in Molecular Recognition

“…The chelation of a Cu(II) ion leads to the formation of three five-membered rings . The two remaining coordination sites on the copper(II) can bind to Lewis basic ligands 18 Fluorescence micrographs of fluorescein labeled 6-His cyt b 5 in the presence of metal-chelating lipid monolayers spread on a buffered subphase (20 mM MOPS, 100 mM NaCl, pH 7.5) at π = 25 mN/m.…”

Homodinuclear RhI and IrI Complexes Derived from Imidazolium‐Benzimidazolates

“…The latter complex contains a functionalised bridging k 1 N : k 1 N benzimidazolato ligand without additional chelation, which is rarely observed in the chemistry of benzimidazole-based ligands. [11] The structure of these complexes in solution is essentially identical to that in the solid state according to an NMR spectroscopic analysis. The two COD ligands present in [RhCl (COD){Rh(μ-1'a)(COD)}] and [RhCl(COD){Rh(μ-1'b)(COD)}] give rise to eight 13 C NMR signals for the CH 2 units in each case.…”

Reversible Coordinative Bonds in Molecular Recognition

“…The chelation of a Cu(II) ion leads to the formation of three five-membered rings . The two remaining coordination sites on the copper(II) can bind to Lewis basic ligands 18 Fluorescence micrographs of fluorescein labeled 6-His cyt b 5 in the presence of metal-chelating lipid monolayers spread on a buffered subphase (20 mM MOPS, 100 mM NaCl, pH 7.5) at π = 25 mN/m.…”

Homodinuclear RhI and IrI Complexes Derived from Imidazolium‐Benzimidazolates

“…The latter complex contains a functionalised bridging k 1 N : k 1 N benzimidazolato ligand without additional chelation, which is rarely observed in the chemistry of benzimidazole-based ligands. [11] The structure of these complexes in solution is essentially identical to that in the solid state according to an NMR spectroscopic analysis. The two COD ligands present in [RhCl (COD){Rh(μ-1'a)(COD)}] and [RhCl(COD){Rh(μ-1'b)(COD)}] give rise to eight 13 C NMR signals for the CH 2 units in each case.…”

Reversible Coordinative Bonds in Molecular Recognition

“…The chelation of a Cu(II) ion leads to the formation of three five-membered rings . The two remaining coordination sites on the copper(II) can bind to Lewis basic ligands 18 Fluorescence micrographs of fluorescein labeled 6-His cyt b 5 in the presence of metal-chelating lipid monolayers spread on a buffered subphase (20 mM MOPS, 100 mM NaCl, pH 7.5) at π = 25 mN/m.…”