Synthesis and Structural Analysis of a 3D Semi-Rigid Cd Coordination Polymer

Cui, Lin; Duan, Jinwei; Zheng, Huayu; Wang, Ying; Wang, Kang

doi:10.1007/s10876-019-01637-1

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“…DPE can induce supramolecular isomerism in coordination polymers, which gives us the possibility to influence magnetism and gas adsorption in these materials (9)(10)(11). DPE is of particular interest due to the possibility of mechanical cocrystallization with the formation of photoactive compounds (12,13), porous organometallic frameworks and photoactive coordination polymers (14,15).…”

Section: Introductionmentioning

confidence: 99%

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

Shaidullina

Sharipova

Volkov

et al. 2023

Photochem & Photobiology

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Photoisomerization of 1,2‐di(4‐pyridyl)ethylene under UV irradiation was studied by NMR and UV spectroscopy in solutions of acetone, acetonitrile and chloroform. It has been established that in the studied solutions under irradiation, geometric photoisomerization occurs: the trans‐isomer transforms into the cis‐isomer and then cyclization occurs. DFT modeling of the listed processes, states and UV absorption spectra of the sample in an acetonitrile solution was performed.

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