2007
DOI: 10.1002/chin.200739131
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Vladimir V. Kouznetsov,
Carlos M. Melendez Gomez,
Juan M. Urbina Gonzalez
et al.

Abstract: A study on interaction between N-(4-pyridinyliden)anilines 1-4 and 2,2-dimethoxypropane under Kametani reaction conditions was realized. According to the GC-MS analysis of crude reaction, besides the needed 4-methyl-2-(4-pyridinyl)quinolines 5-8, three collateral products: secondary amines 9-12, 4-(2-methylprop-1-enyl)quinolines 13-16 and 4-(2-methoxy-2-methylpropyl)quinolines 17-20 were formed. Unexpected quinolines 13-16 as well the desired quinolines 5-8 were isolated and fully characterized. In contrast, …

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