volume 6, issue 66, P61630-61640 2016
DOI: 10.1039/c6ra09803g
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Abstract: In this work, a well-fined amphiphilic polyhedral oligomeric silsesquioxane (POSS) star-shaped inorganic/organic hybrid block copolymers with poly(ε-caprolactone)-poly(2-(dimethylamino)ethyl methacrylate)-co-poly(ethylene glycol) methacrylate) (POSS-PCL-P(DMAEMA-co-PEGMA)) 16 were synthesized with different PCL segments via thiol-ene click reaction, ring opening polymerization (ROP) and atom transfer radical polymerization (ATRP), which were confirmed by Fourier transforms infrared spectroscopy (FT-IR), proto…

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