volume 2, issue 2, P266-268 2011
DOI: 10.5155/eurjchem.2.2.266-268.227
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Abstract: KEYWORDSDimanganese(II) complexes [Mn2(bonp)(PhCO2)2]PF6 (1) and [Mn2(bocp)(PhCO2)2]PF6 (2) were synthesized with p-nitro-and p-chloro-substituted phenol-based dinucleating ligands bonp -[2,6-bis[bis(2-methoxyethyl)aminomethyl]-4-nitrophenolate anion] and bocp -[4chloro-2,6-bis[bis(2-methoxyethyl)aminomethyl]phenolate anion], respectively, with the aim of controlling the redox potentials of the dimanganese center by changing the p-substituents in the dinucleating ligands. Cyclic voltammograms of 1 and 2 showe…

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