Synthesis and crystal structure of the zinc complex [Zn(P(py)3)2][Zn(NCS)4](MeCN)

Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh2(3-OCH2C5H4N)

“…The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/ biligand ring-forming abilities. 23,[25][26][27][28][29][30][31][32][33][34][35][36][37][38][43][44][45][46][47][48][49][51][52][53][54][55][56] Relatively little work has been reported for 3-and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. 34,37,49 Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present.…”

“…Pyridyl-substituted phosphines, which were first reported nearly 60 years ago, have become commonplace and have been thoroughly explored since their introduction. ,,− ,− They are an interesting family of ligands because they have the potential to display both the hard- and soft-donating abilities of the nitrogen and phosphorus, respectively, in a single moiety. The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/biligand ring-forming abilities. ,− ,− ,− Relatively little work has been reported for 3- and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. ,, Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present. This excludes a vast array of complexes that could be formed by separating the nitrogen and phosphorus to the point of minimal interaction.…”

Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh2(3-OCH2C5H4N)

“…The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/ biligand ring-forming abilities. 23,[25][26][27][28][29][30][31][32][33][34][35][36][37][38][43][44][45][46][47][48][49][51][52][53][54][55][56] Relatively little work has been reported for 3-and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. 34,37,49 Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present.…”

“…Pyridyl-substituted phosphines, which were first reported nearly 60 years ago, have become commonplace and have been thoroughly explored since their introduction. ,,− ,− They are an interesting family of ligands because they have the potential to display both the hard- and soft-donating abilities of the nitrogen and phosphorus, respectively, in a single moiety. The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/biligand ring-forming abilities. ,− ,− ,− Relatively little work has been reported for 3- and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. ,, Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present. This excludes a vast array of complexes that could be formed by separating the nitrogen and phosphorus to the point of minimal interaction.…”

Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh2(3-OCH2C5H4N)

“…The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/ biligand ring-forming abilities. 23,[25][26][27][28][29][30][31][32][33][34][35][36][37][38][43][44][45][46][47][48][49][51][52][53][54][55][56] Relatively little work has been reported for 3-and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. 34,37,49 Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present.…”

“…Pyridyl-substituted phosphines, which were first reported nearly 60 years ago, have become commonplace and have been thoroughly explored since their introduction. ,,− ,− They are an interesting family of ligands because they have the potential to display both the hard- and soft-donating abilities of the nitrogen and phosphorus, respectively, in a single moiety. The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/biligand ring-forming abilities. ,− ,− ,− Relatively little work has been reported for 3- and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. ,, Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present. This excludes a vast array of complexes that could be formed by separating the nitrogen and phosphorus to the point of minimal interaction.…”

Two-, Three-, and Four-Coordinate Ag(I) Coordination Polymers Formed by the Novel Phosphinite PPh2(3-OCH2C5H4N)

“…The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/ biligand ring-forming abilities. 23,[25][26][27][28][29][30][31][32][33][34][35][36][37][38][43][44][45][46][47][48][49][51][52][53][54][55][56] Relatively little work has been reported for 3-and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. 34,37,49 Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present.…”

“…Pyridyl-substituted phosphines, which were first reported nearly 60 years ago, have become commonplace and have been thoroughly explored since their introduction. ,,− ,− They are an interesting family of ligands because they have the potential to display both the hard- and soft-donating abilities of the nitrogen and phosphorus, respectively, in a single moiety. The majority of reports in this area have been of 2-pyridylphosphines, with their chelating or bimetallic/biligand ring-forming abilities. ,− ,− ,− Relatively little work has been reported for 3- and 4-pyridylphosphines, most likely because of the difficulty with which they are synthesized. ,, Using only 2-pyridyl substituents, the arrangement of the complexes formed is inherently limited to those discrete structures that can be obtained with the acute angles present. This excludes a vast array of complexes that could be formed by separating the nitrogen and phosphorus to the point of minimal interaction.…”