Aluminum I 2100Synthesis and Characterization of a New Organically Templated Aluminophosphite with a Chainlike Structure. -Title compound (II) crystallizes in the triclinic space group P1 with Z = 2 (single crystal XRD). The structure consists of distorted octahedral AlO6 and pseudo pyramidal HPO3 units, which are connected via corners to form a chain-like framework with a Al/P ratio of 1:2. The organic templates are fully protonated and interact with the aluminophosphite chains through extensive hydrogen bon…
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