Syntheses and molecular structures of 18/16-electron half-sandwich iridium(III) complexes with chelating anilido-imine ligands

Preparation of Aluminum Hydrides with Chelating Anilido‐Imine Ligands by Addition of an Al–H Bond to a C=N Bond

“…To date, some alkylaluminum, [10] nickel, [11] copper, [12] zinc, [13] yttrium, [14] boron, [15] iridium, [16] and platinum [17] complexes bearing such ligands have been prepared and their catalytic properties have also been investigated. …”

Synthesis and Characterization of Nickel(II) and Palladium(II) Complexes based on Tridentate [N–NP] and [N–NS] Ligands and Their Applications in Norbornene Polymerization

“…Previously, our group have reported Ni and Ir complexes containing anilido-imine ligands for ethylene and norbornene polymerization. , Moreover, we have successfully obtained the group IV metal complexes bearing the ligands which providing a soft atom coordinated to the metal center and demonstrated the positive effect of the soft atom in the ligands for ethylene polymerization. ,, Despite the fact that the introduction of a soft S atom to anilido-imine ligands on the amido nitrogen has been reported, there have been no examples of modifying the anilido-imine liands on the imine nitrogen side with soft atoms. Following our interest in modifying anilido-imine ligands by the side arm using soft atoms and exploring the effect of a pendant arm on the imine nitrogen, a series of novel tridentate anilido-imine [N – NS] and [N – NP] ligands and their nickel(II) and palladium(II) complexes have been synthesized.…”