2007
DOI: 10.1002/chin.200740163
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Mukesh Chandra Joshi,
Gopal Singh Bisht,
Diwan S. Rawat

Abstract: Syntheses and Antibacterial Activity of Phendioxy Substituted Cyclic Enediynes.-Reaction of dihydroxybenzaldehyde (VI) and imines (X) with dibromooctenediyne (VII) in the presence of potassium carbonate afford the 13-membered cyclic enediynes (VIII) and (XI), resp., whereas under identical reaction conditions, the reaction of resorcinol (I) with (VII) results in decomposition of the dibromoenediyne precursor. Alternatively, enediyne (V) is obtained by reaction of (I) with propargyl bromide (II), followed by S…

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