In models of thick wall electroweak baryogenesis a common assumption is that the plasma interacting with the expanding Higgs bubble wall during the electroweak phase transition is in kinetic equilibrium (or close to it). We point out that, in addition to the requirement of low wall velocity, kinetic equilibrium requires that the change in the momentum of the particles due to the force exerted by the wall should be much less than that due to scattering as the plasma passes through the wall. We investigate whether this condition is satisfied for charginos and neutralinos participating in thick wall supersymmetric electroweak baryogenesis PACS numbers: 98.80.CqStandard electroweak baryogenesis models attempt to create the observed baryon asymmetry of the universe during the electroweak phase transition by the interaction of the expanding Higgs bubble wall with the ambient plasma. In models in which the thickness of the bubble wall is greater than the mean free path of particles passing through the bubble wall the Higgs field is treated as a classical background field for the plasma traversing the wall. These thick wall electroweak baryogenesis models make certain assumptions regarding the thermal nature of the plasma. In particular, it is assumed that the plasma is in kinetic equilibrium (or close to it) as it passes through the wall. In this Brief Report we shall highlight a condition for the validity of this assumption that has not been discussed elsewhere while estimating the baryon asymmetry.The thermal assumption in thick wall electroweak baryogenesis models is indicated by the form of the perturbed thermal particle distribution function substituted in the kinetic equation in the semi-classical force mechanism of Refs. [1,2,3,4,5], in the adoption of a thermal density matrix (for calculating various sources) and the diffusion approximation (J = −D(T )∇n) in the wall in Ref. [6], and in the choice of thermal equilibrium Green's functions while evaluating the source in the Closed Time Path formalism of Refs. [7,8,9,10,11]. The thermal assumption is justified by arguing that departures from kinetic equilibrium are small for v w ≪ 1 or Γl w /v w ≫ 1, where l w and v w are the wall width and velocity and Γ is the rate of interactions that maintain kinetic equilibrium. This picture of maintaining kinetic equilibrium inside the bubble wall is valid only if the momentum transferred to the particles due to their interaction with the wall is very small compared to the effect of collisions. Below we argue that satisfying this requirement provides an additional condition, independent of the wall velocity.Unless the change in momentum of the particles due to scattering in the plasma is much greater than the change due to the action of the background Higgs field, the particles in the bubble wall will acquire a directed velocity and will no longer have a randomly directed particle velocity distribution, as in kinetic equilibrium. In plasmas where a background electric field acts over the entire bulk of the plasma, this happe...