1996
DOI: 10.1002/(sici)1099-0518(199605)34:7<1271::aid-pola14>3.0.co;2-6
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Study of the thermal decomposition of potassium persulfate by potentiometry and capillary electrophoresis
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1997
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Cited by 38 publications
(27 citation statements)
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“…7), the different initiators resulted in similar final particle sizes. No apparent effect was observed as a function of the radicals being negatively charged upon dissociation (SO 4 −• for APS and KPS),61 or neutral (OH • for HPO),51 in agreement with the results shown by Boutti et al51…”
Section: Resultssupporting
confidence: 89%
“…7), the different initiators resulted in similar final particle sizes. No apparent effect was observed as a function of the radicals being negatively charged upon dissociation (SO 4 −• for APS and KPS),61 or neutral (OH • for HPO),51 in agreement with the results shown by Boutti et al51…”
Section: Resultssupporting
confidence: 89%
“…The kinetic study showed that MW-assisted decomposition kinetics of K 2 S 2 O 8 in aqueous solutions follows first-order rate law similar to the thermal heating mode, as also documented in previous studies. ,− Excellent fits with correlation coefficient R 2 higher than 0.999 with more than 200 data points were obtained in linear regression for the calculation of the rate constants according to − ln ( 1 − X A ) = k t …”
Section: Resultssupporting
confidence: 76%
“…The rate of entry was calculated to be ρ N p = 3.49 × 10 16 (entries/s)/L. In our experiment, the rate of initiator decomposition was 2 f k d [I] N a = 9.7 × 10 16 (rad/s)/L . Thus, in this particular case, we found an efficiency (ratio of entrant to produced radicals) of 36%.…”
supporting
confidence: 49%
