Study of Adsorption Performance of Biochar for Heavy Metals Removal

The application of layered double hydroxides (LDHs) of MgFe and its composites with biochar of Eucalyptus camdulensis (Eb) and ethylenediaminetetraacetic acid (EDTA) was explored in a batch study to mitigate toxic lead ions (Pb2+) from synthetic wastewater solutions. SEM images revealed that MgFe/LDH composites with Eb were successfully formed, while FTIR spectra confirmed the successful adsorption of Pb2+ onto the MgFe/LDH and composite adsorbents. Batch equilibrium was attained after 60 min, then the adsorption capacity gradually increased. An increase in adsorption capacity (and a 60% decrease in the percentage removal) was observed by increasing the initial Pb2+ concentration, and the highest value was 136 mg g-1 for MgFe/LDH-Eb_EDTA. A 50–60% increase in both the adsorption capacities and percent removal was seen in the pH range of 2–6. The second-order kinetic model had a nearly perfect fitting, suggesting that chemisorption was the mechanism controlling adsorption. The Langmuir isotherm model best presented the adsorption data, suggesting that the Pb2+ adsorption was monolayer, and predicted a better affinity between the adsorbent surface and absorbed Pb2+ for MgFe/LDH-Eb_EDTA in comparison to the other two adsorbents. The D–R isotherm suggested that the adsorption system was physical based on E values for all three adsorbents, while the Temkin isotherm model suggested that Pb2+ adsorption was heterogeneous. Finally, the Sips and R–P isotherms predicted that the adsorption of Pb2+ on the surface of the adsorbents was homogeneous and heterogeneous.

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Ethylenediaminetetraacetate functionalized MgFe layered double hydroxide/biochar composites for highly efficient adsorptive removal of lead ions from aqueous solutions

Amin

Alazba

Shafiq

2022

PLoS ONE

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Preparation of hydrogels based on poplar cellulose and their removal efficiency of Cd(II) from aqueous solutions

Zhang

Zhang²,

Jiang

et al. 2023

Journal of Water and Health

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Industrial heavy metal-contaminated wastewater is one of the main water pollution problems. Adsorbents are a promising method for the removal of heavy metal contaminants. Herein, polyaspartic acid/carboxymethyl poplar sawdust hydrogels (PASP/CMPP) and ascorbic acid/carboxymethyl poplar sawdust hydrogels (VC/CMPP) were prepared by aqueous polymerization using alkalized poplar sawdust (CMPP) as the substrate and PASP and vitamin C (VC) as modifiers. The effective results, provided by the characterization analysis of SEM and BET, indicate that the surface of the PASP/CMPP hydrogel has a larger number of loose pores and a larger pore volume than the VC/CMPP hydrogel. The treatment effects of the two hydrogels on simulated wastewater containing Cd(II) were investigated by a batch of experiments. The results showed that PASP/CMPP had a better adsorption effect than VC/CMPP under the same adsorption conditions. Interestingly, the solid concentration effect was found in the process of sorption kinetics and sorption isotherms. The sorption kinetic curves of Cd(II) on PASP/CMPP were well-fitted by the quasi-second-order kinetics under different adsorbent concentrations. The adsorption conforms to Langmuir and Freundlich adsorption isotherm models. More importantly, PASP/CMPP composites are expected to be used as a new kind of environmental adsorbent for wastewater treatment.

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Biochar: Production, Applications, and Market Prospects in Portugal

García¹,

Alves²,

Rijo³

et al. 2022

Environments

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Biochar produced during the thermochemical decomposition of biomass is an environmentally friendly replacement for different carbon materials and can be used for carbon sequestration to mitigate climate change. In this paper, current biochar production processes and top market applications are reviewed, as well as emerging biochar uses gaining momentum in the market. Various application fields of biochar, including agricultural applications (e.g., soil conditioning), adsorption (for soil and water pollutants), carbon sequestration, catalysis, or incorporation into composites or construction materials, are also presented and discussed. According to this literature overview, slow pyrolysis is the preferred process for biochar production, whereas agricultural applications (for soil conditioning and fertilization) are the most studied and market-ready solutions for biochar use. The Alentejo region (Portugal) shows tremendous potential to be a major player in the developing biochar market considering feedstock availability and large areas for biochar agricultural application. Biochar’s production potential and possible benefits were also estimated for this Portuguese region, proving that agricultural application can effectively lead to many environmental, economic, and social gains.

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Study of Adsorption Performance of Biochar for Heavy Metals Removal

Cited by 3 publications

References 22 publications

Ethylenediaminetetraacetate functionalized MgFe layered double hydroxide/biochar composites for highly efficient adsorptive removal of lead ions from aqueous solutions

Ethylenediaminetetraacetate functionalized MgFe layered double hydroxide/biochar composites for highly efficient adsorptive removal of lead ions from aqueous solutions

Preparation of hydrogels based on poplar cellulose and their removal efficiency of Cd(II) from aqueous solutions

Biochar: Production, Applications, and Market Prospects in Portugal

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