Studies on the thermal decomposition of ferric acetate

Jewur, S. S.; Kuriacose, J. C.

doi:10.1016/0040-6031(77)85107-1

Cited by 42 publications

(28 citation statements)

References 2 publications

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“…Decomposition path has been previously proposed for three of the considered compounds [13][14][15][16]; in this cases we have verified that our data are concerted with earlier propositions. Decomposition path has been previously proposed for three of the considered compounds [13][14][15][16]; in this cases we have verified that our data are concerted with earlier propositions.…”

Section: Decomposition Reactionssupporting

confidence: 91%

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Thermal decomposition of the [Co(NH3)6]Cl3, Co[(NH3)4Cl2]Cl, K3[Fe(C2O4)3]3H2O and Fe(CH3COO)3 in argon and air atmosphere

Wojciechowska

Brągiel

Czerwiński³

1990

Journal of Thermal Analysis

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Section: Decomposition Reactionssupporting

confidence: 91%

“…Fe(III) acetate decomposition has been studied by Jewur and Kuriaeose [13]. They have found that decomposition carries out Fe203, CO2 and CH3COCH3.…”

Section: Decomposition Reactionsmentioning

confidence: 99%

Thermal decomposition of the [Co(NH3)6]Cl3, Co[(NH3)4Cl2]Cl, K3[Fe(C2O4)3]3H2O and Fe(CH3COO)3 in argon and air atmosphere

Wojciechowska

Brągiel

Czerwiński³

1990

Journal of Thermal Analysis

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“…A literature survey also shows that some other properties such as fluorescence [12] and magnetism [13][14][15] have attracted the attention of other workers. Jewar [16], Duval [t 7] and Judd [18] have extensively studied the decomposition kinetics of some metal acetates. Bass [19] and Alexandrov [20] have reported the decomposition kinetics of a few short chain metal carboxylates.…”

mentioning

confidence: 99%

Pyrolytic decomposition of some even chain length copper (II) carboxylates

Akanni

Ajayi

Lambi

1986

Journal of Thermal Analysis

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The products of the pyrolytic decomposition of some even chain-length copper (II) carboxylates from decanoate to octadecanoate inclusive have been identified, using a flow system, to be copper, carbon dioxide, a carboxylic acid and an odd chain-mength alkene. These products are similar to those reported for the decomposition of mercury(lI) carboxylates. The unexpectedly low (less than unity) CO2/soa p ratio was attributed to the reduction of the CO 2 to carbon monoxide. The carboxylic acid was characterised by wet chemical tests, determining the melting points of the acid and its amide derivative and matching its IR spectrum with that of the authentic acid. Elemental analysis and wet chemical tests were employed for the identification of the alkene.The products of decomposition and mechanism proposed to account for the degradative route of the systems show that good quality thin solid copper oxide films may only be obtained from the decomposition of copper(II), carboxylates if the carrier gas is non-inert (e.g. oxygen).Most of the previous studies in this laboratory [1][2][3][4][5][6][7][8] and elsewhere [9-11] on metal carboxylates (soaps) have focussed attention mainly on their physical properties in the molten phase. For example, in our laboratory, the electrical conductivity, viscosity and heat of phase changes of lead [1,3,6]

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“…Therefore, as XRD affirmed that the sample is free from hematite, FT-IR assured that the synthesized nanofibers are free from magnetite. Previous study [40] about the decomposition of ferric acetate in an inert atmosphere indicated that c-Fe 2 O 3 is the final product. Analogous to that study, decommission of ferrous acetate in our study to c-Fe 2 O 3 can be explained by this equation…”

Section: Resultsmentioning

confidence: 99%

Synthesis and characterization of maghemite iron oxide (γ-Fe2O3) nanofibers: novel semiconductor with magnetic feature

Barakat

2012

J Mater Sci

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Among the reported nanostructural shapes, nanofibers have special interest due to the long axial ratio which has a distinct impact on many chemical and physical properties. In this study, synthesis of the desirable maghemite iron oxide (c-Fe 2 O 3 ) nanofibers is introduced. Calcination of electrospun mats composed of ferrous acetate and poly(vinyl alcohol) in argon atmosphere resulted in producing maghemite nanofibers. Detailed characterization affirmed that the obtained c-Fe 2 O 3 nanofibers are free of other iron oxides. Due to the axial ratio impact, the synthesized nanofibers which have an average diameter of *70 nm do have magnetic properties resemble c-Fe 2 O 3 nanoparticles having an average diameter of *5 nm. Accordingly, the produced nanofibers are considerable candidate for biomagnetic separation of the biomaterials. The prepared c-Fe 2 O 3 nanofibers can be easily handled as they were obtained in the form of strong mats. Electrical properties study indicated that the introduced nanofibers behave as a semiconducting material. Moreover, the synthesized c-Fe 2 O 3 nanofibers have band gap energy of *4.2 eV. Based on the simplicity, effectiveness, highyield, and low-cost features of the utilized preparation process and the studied physiochemical properties of the obtained product, the synthesized c-Fe 2 O 3 nanofibers might have considerable application fields.

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Studies on the thermal decomposition of ferric acetate

Cited by 42 publications

References 2 publications

Thermal decomposition of the [Co(NH3)6]Cl3, Co[(NH3)4Cl2]Cl, K3[Fe(C2O4)3]3H2O and Fe(CH3COO)3 in argon and air atmosphere

Thermal decomposition of the [Co(NH3)6]Cl3, Co[(NH3)4Cl2]Cl, K3[Fe(C2O4)3]3H2O and Fe(CH3COO)3 in argon and air atmosphere

Pyrolytic decomposition of some even chain length copper (II) carboxylates

Synthesis and characterization of maghemite iron oxide (γ-Fe2O3) nanofibers: novel semiconductor with magnetic feature

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