1926
DOI: 10.1021/ja01419a026 View full text |Buy / Rent full text
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Abstract: The reaction between acetamide and alkyl bromides, showing its general applicability to the synthesis of substituted acetamides and the corresponding amines, has been investigated.A possible mechanism for the reaction, accounting for the production of ammonium bromide, has been suggested.1. 2.During a study of the pharmacological properties of some iso-urea derivatives, it was found by one of us1 that carbethoxy-ethyl-isourea had well-marked physiological action, the chief effects being a mild central depressi… Show more

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“…1/[σ 2 (Fo 2 ) + (aP) 2 + bP] where P = (Fo 2 + 2Fc 2 )/3 was introduced. Towards the end of the refinement, it was determined that the Cl2 atom was disordered.…”
Section: X-ray Crystallographymentioning
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“…1/[σ 2 (Fo 2 ) + (aP) 2 + bP] where P = (Fo 2 + 2Fc 2 )/3 was introduced. Towards the end of the refinement, it was determined that the Cl2 atom was disordered.…”
Section: X-ray Crystallographymentioning
“…[EtOC(=O)N(H)C(=N + H2)NH2]Cl.½H2O (1), is described. While the precursor compound, EtOC(=O)N(H)C(=NH)NH2, was first prepared about 150 years ago [1,2], a search of the literature revealed no definitive evidence for 1 although hydrochloride salts have been alluded…”
Section: Introductionmentioning