Structure des solutions dans l'eau des halogénures de zinc et de cadmium

Diffraction Studies of the Structure of Liquids.

“…Debot's study (91) of zinc and cadmium chloride solutions is based on the unlikely assumption that linear molecules of ZnCl2 and CdCl2 exist in solution, and the resulting distribution function is supposed to give the distribution of these molecules. In another study (215) 3 chlorine neighbors at 2.28 Á. and one water neighbor at 2.05 are assigned to each zinc in 27.5 molal zinc chloride solution, which is virtually molten ZnCl2'2H20.…”