The magnetic, structural and microstructural properties of bulk La 1Àx Pr x MnO 3þ have been studied as a function of Pr doping. Magnetization versus temperature measurements show that La 0.8 Pr 0.2 MnO 3þ undergoes one magnetic transition, while La 0.7 Pr 0.3 MnO 3þ and La 0.5 Pr 0.5 MnO 3þ exhibit two magnetic transitions. X-ray diffraction and transmission electron microscopy studies indicate that all these compounds share an orthorhombic structure, which is derived from and also closely related to the ideal perovskite structure. Besides physical properties, the salient contrast between microstructures in these compounds is that there are high-density oriented microdomains in La 0.8 Pr 0.2 MnO 3þ , whereas La 0.7 Pr 0.3 MnO 3þ and La 0.5 Pr 0.5 MnO 3þ are free of these microstructural characteristics. A possible mechanism of domain formation is discussed.