Multiple-wave X-ray reflections usually aggravate the measurement of Bragg reflections, especially of weak "forbidden" reflections. Accurate analysis of multiple-wave peaks usually allows to avoid this. However, multiple-wave reflections can also provide information about crystal structure, since crystal cell parameters determine the positions of multi-wave peaks. The forbidden reflections 002 and 100 in paratellurite are measured and an approach based on semi-kinematical X-ray scattering used to handle the multiple-wave interferences is shown here.