2007
Abstract: The structures, bonding, and ring-opening reactions of strained cyclic carbon-based molecules form a key component of standard textbooks. In contrast, the study of strained organometallic molecules containing transition metals is a much more recent development. A wealth of recent research has revealed fascinating nuances in terms of structure, bonding, and reactivity. Building on initial work on strained ferrocenophanes, a broad range of strained organometallic rings composed of a variety of different metals, …
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Cited by 218 publications
(175 citation statements)
References 222 publications
(194 reference statements)
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“…Each of these isomers converts into two when the inversion at P is contemplated. 6 Therefore two meso, two mixed and two racemic mixtures could be generated. The isomers resulting from P inversion need to be accounted for because typical inversion barriers for tertiary phosphines are in the range 28-36 kcal·mol -1 .…”
Section: Synthesis Of Mono and Diansa Cobaltabisdicarbollidephane Animentioning
confidence: 99%
“…On the other hand, for oxidized anions [4] -, [5] -and [6] -there is no interaction between phosphorus and cobalt due to the absence of the P lone pair, which is bonded to the chalcogen atoms ( Figure 12). The interactions found in these compounds are between the P-C c bonds and the empty 4s orbital of cobalt with a similar energy of ca.…”
Section: Synthesis Of Mono and Diansa Cobaltabisdicarbollidephane Animentioning
confidence: 99%
“…[1][2][3][4][5][6][7] Moreover, it counts among the very few metallopolymers accessible by living chain-growth protocols which give access not only to products of defined molar mass and narrow polydispersity but also to a broad variety of copolymer architectures: plenty of PFDMS block copolymers with, e.g., polystyrene (PS), [8][9][10][11] polyisoprene (PI), [12] poly(dimethyl siloxane) (PDMS), [8,12,13] poly(ethylene oxide) (PEO), [14] poly(methyl methacrylate) (PMMA), [15][16][17][18][19][20][21] and poly(2-vinylpyridine) [22] have been synthesized, and they have been shown to develop fascinating morphologies at the nanometer to micrometer scale. [2,7,23] Another important feature of PFDMS is its ability to crystallize.…”
Section: Introductionmentioning
confidence: 99%
“…1 Thus, analogues of PFS with other elements in the bridge or containing different metals to iron (in some cases in combination with alternative π-hydrocarbon ligands) have been prepared and their ROP has been successfully demonstrated in a growing number of cases. This provides a route to new and fascinating metallopolymers with modified properties, 222,[399][400][401][402][403][404][405] and studies of these materials are likely to constitute a broad new area of future research.…”
Section: Summary and Future Workmentioning
confidence: 99%
“…A related galla[1]ferrocenophane was published by Lund et al (2006). For related literature, see: Bellas & Rehahn (2007) ;Foucher et al (1992); Herbert et al (2007); Lund et al (2007); Osborne & Whiteley (1975); Schachner et al (2005aSchachner et al ( , 2007.…”
Section: Related Literaturementioning
confidence: 99%
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