“…At the plume fringe steep concentration gradients of dissolved reactants develop and have been observed at high-resolution monitored field sites (e.g., Amos et al, 2011;Davis et al, 1999;Prommer et al, 2009;Thornton et al, 2001;Tuxen et al, 2006). Insufficient mixing between dissolved reactants is increasingly recognized to control the overall contaminant transformation rates (e.g., Chiogna and Bellin, 2013;Cirpka et al, 2012;Kitanidis, 1994;Sanchez-Vila et al, 2007), and thus, the potential for natural attenuation and the performance of in situ engineered remediation. Therefore, correct characterization and quantification of mixing is of utmost importance to accurately describe reactive solute transport in groundwater.…”