Abstract. Extended tailing of tracer breakthrough is often observed in pulse injection tracer tests conducted in fractured geologic media. This behavior has been attributed to diffusive exchange of tracer between mobile fluids traveling through channels in fractures and relatively stagnant fluid between fluid channels, along fracture walls, or within the bulk matrix. We present a field example where tracer breakthrough tailing apparently results from nondiffusive transport. Tracer tests were conducted in a fractured crystalline rock using both a convergent and weak dipole injection and pumping scheme. Deuterated water, bromide, and pentafluorobenzoic acid were selected as tracers for their wide range in molecular diffusivity. The late time behavior of the normalized breakthrough curves were consistent for all tracers, even when the pumping rate was changed. The lack of separation between tracers of varying diffusivity indicates that strong breakthrough tailing in fractured geologic media may be caused by advective transport processes. This finding has implications for the interpretation of tracer tests designed to measure matrix diffusion in situ and the prediction of contaminant transport in fractured rock.
IntroductionPulse injection tracer tests conducted in fractured rocks typically result in a recovered concentration history (breakthrough) that is highly skewed to later times, particularly when compared to advection and dispersion in unconsolidated porous media. The most common explanation for this "breakthrough tailing" is that while some of the tracer moves quickly through open channels, a significant fraction of the tracer is delayed by diffusive exchange with the rock matrix. Tracer mass that moves primarily through open channels results in an early peak in concentration, while the tracer that is heavily influenced by diffusive exchange results in a low concentration "tail" over an extended period of time. The exchange of mass between relatively mobile fluid in the fracture and relatively immobile fluid in the rock matrix is usually called "matrix