Abstract:Analysis of the products of solvolysis of aryl esters of anilidophosphoric acids in water-2-propanol mixture excludes that the reaction proceeds via E1cB mechanism. Analysis of the reaction products of solvolysis of methyl-substituted compounds made it possible to evaluate the importance of the reported steric hindrance by CH3 group. The dependence of rate constants of the solvolysis on solvent system has been established.
scite is a Brooklyn-based startup that helps researchers better discover and evaluate scientific articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by researchers from dozens of countries and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.