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“…[8][9][10][11][12]43,44 In all instances for which a crystal structure was also reported, the five-membered pyrrolidine ring was found to reside in a cisoid fashion on the same side of the plane defined by the prolinate chelate ring. [8][9][10][11][12]43,44 In all instances for which a crystal structure was also reported, the five-membered pyrrolidine ring was found to reside in a cisoid fashion on the same side of the plane defined by the prolinate chelate ring.…”
Section: Structuresmentioning
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rupbmjkragerfmgwileyiopcupepmcmbcthiemesagefrontiersapsiucrarxivemeralduhksmucshluniversity-of-gavle
“…[8][9][10][11][12]43,44 In all instances for which a crystal structure was also reported, the five-membered pyrrolidine ring was found to reside in a cisoid fashion on the same side of the plane defined by the prolinate chelate ring. [8][9][10][11][12]43,44 In all instances for which a crystal structure was also reported, the five-membered pyrrolidine ring was found to reside in a cisoid fashion on the same side of the plane defined by the prolinate chelate ring.…”
Section: Structuresmentioning
“…43,44 However, further deprotonation of 20 (a product of deprotonation, itself!) Conceivably, this may arise via either of two paths.…”
Section: Structuresmentioning
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“…Equilibrium studies on analogous diastereoisomeric N-methyl alanine chelate (13) indicate the stable conformer is that with the methyls trans to each other. We infer therefore that D20 will add in preference to the carbanion trans to the benzyl group.…”
Section: Synthesis Of Chiral Glycine Nh2c(h)(d)coohmentioning