Abstract:A simple self-assembled [Pd2 L4 ] coordination cage consisting of four carbazole-based ligands was found to dimerize into the interpenetrated double cage [3 X@Pd4 L8 ] upon the addition of 1.5 equivalents of halide anions (X=Cl(-) , Br(-) ). The halide anions serve as templates, as they are sandwiched by four Pd(II) cations and occupy the three pockets of the entangled cage structure. The subsequent addition of larger amounts of the same halide triggers another structural conversion, now yielding a triply cate… Show more
“…Zhu et al 67 not result in the formation of defined complexes. Therefore, this synthesis represents an unusual example of a tetrafluoroborate peripherally templated structure.…”
Section: Self-assembling Systems Involving Anionsmentioning
“…Zhu et al 67 not result in the formation of defined complexes. Therefore, this synthesis represents an unusual example of a tetrafluoroborate peripherally templated structure.…”
Section: Self-assembling Systems Involving Anionsmentioning
“…Surprisingly, addition of an excess of halide ions resulted in displacement of ligands to give a metallo- [3]-catenane composed of three interlocked dinuclear metallocycles (Fig 15). 69 Please do not adjust margins Please do not adjust margins …”
Section: Stimuli Responsive Assembly and Disassembly Of Mimsmentioning
The use of metal ions to template the synthesis of catenanes by Sauvage and co-workers was a pivotal moment in the development of the field of interlocked molecules. In this Review Article we shall examine the different roles metal-ligand interactions play in modern syntheses of interlocked molecules and materials, with a particular focus on seminal contributions and the advantages and disadvantages of employing metal ligand interactions.
“…Yoshizawa wechselte zwischen Quecksilber(II)‐basierten Ringen und Käfigen durch die Ligand‐zu‐Metall‐Stöchiometrie 11. Unsere Arbeitsgruppe wandelte durch Halogenidionen monomere [Pd2L4]‐Käfige zu interpenetrierten [Pd4L8]‐Doppelkäfigen um und dann weiter zu einem Triple‐Catenan (Abbildung 4) 12…”
Käfigverbindungen, die Gastmoleküle in ihr Inneres aufnehmen und wieder frei setzen, eignen sich als Rezeptoren, Transporter und supramolekulare Katalysatoren — erst recht, wenn sie sich über Licht und Signalmoleküle steuern lassen.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.