2016
DOI: 10.1115/1.4031199
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Abstract: Chemical kinetic models are being developed for the γ-radiolysis of subcritical and supercritical water (SCW) to estimate the concentrations of radiolytically produced oxidants. Many of the physical properties of water change sharply at the critical point. These properties control the chemical stability and transport behavior of the ions and radicals generated by the radiolysis of SCW. The effects of changes in the solvent properties of water on primary radiolytic processes and the subsequent aqueous reaction …

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