Stabilization of Ferroelectric Phase in Highly Oriented Quinuclidinium Perrhenate (HQReO4) Thin Films

Abstract

The low-temperature processability of molecular ferroelectric (FE) crystals makes them a potential alternative for perovskite oxide-based ferroelectric thin films. Quinuclidinium perrhenate (HQReO4) is one such molecular FE crystal that exhibits ferroelectricity when crystallized in an intermediate temperature phase (ITP). However, bulk HQReO4 crystals exhibit ferroelectricity only for a narrow temperature window (22 K), above and below which the polar phase transforms to a non-FE phase. The FE phase or ITP of HQReO4 should be stabilized in a much wider temperature range for practical applications. Here, to stabilize the FE phase (ITP) in a wider temperature range, highly oriented thin films of HQReO4 were prepared using a simple solution process. A slow evaporation method was adapted for drying the HQReO4 thin films to control the morphology and the temperature window. The temperature window of the intermediate temperature FE phase was successfully widened up to 35 K by merely varying the film drying temperature between 333 and 353 K. The strategy of stabilizing the FE phase in a wider temperature range can be adapted to other molecular FE materials to realize flexible electronic devices.

Ferroelectric Crystals of Globular Molecules: Cambridge Structural Database Mining and Computational Assessment

“…Several systems containing variations of the quinuclidinium molecule have been studied in recent years. ,,,,– ,, Notably, Tang et al reported a Curie temperature of 466 K for [F-C 7 H 13 N]­ReO 4 . Another material of interest is [C 7 H 14 N]­IO 4 , for which You et al found 12 equivalent directions of polarization .…”

“…Several systems containing variations of the quinuclidinium molecule have been studied in recent years. 6,18,21,28,[67][68][69]81,82 17 The reported coercive fields of these Table 2. continued a Values have been listed for the melting temperatures T melt.…”

Acrylate and Methacrylate Polymers’ Applications: Second Life with Inexpensive and Sustainable Recycling Approaches

“…The design and development of new, highly efficient systems for food industry [ 1 , 2 ], electronic [ 3 , 4 ], information science [ 5 , 6 ] biomedicine [ 7 , 8 ] and environmental [ 9 , 10 ] applications constitute an important challenge. For such ambitious purpose it is mandatory to choose ecofriendly materials or recyclable ones, showing wide versatility in terms of structure and physicochemical properties [ 11 , 12 ].…”