volume 23, issue 1-2, P7-12 2003
DOI: 10.1016/s0928-4931(02)00227-8
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B Pignataro, A Licciardello, S Cataldo, G Marletta

Abstract: The nanoelectrochemical modification of alkyl self-assembled monolayers (SAMs) obtained on hydrogenated silicon surfaces via radical-initiated reactions of 1-octadecene has been investigated. Scanning Probe Microscopy (SPM) showed that the modification of the organic layer occurs by applying either positive or negative biases to the tip at a threshold of about ±5 V. When the bias absolute value was ≤6 V, the height of the monolayer was only faintly modified, whereas a consistent increase in tip/sample friction…

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