2013
DOI: 10.3762/bjoc.9.39
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Abstract: SummaryThe article deals with coordination compounds of iron(II) that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure and irradiation with light. The spin states involved have different magnetic and optical properties suitable for their detection and characterization. Spin crossover compounds, though known for more than eight decades, have become most attractive in rec… Show more

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Cited by 633 publications
(602 citation statements)
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“…There is a unique crystallographically-independent molecule. The crystal involves two molar methanol molecules; namely, the composition formula is [Fe(CH 3 S-pybox) 2 ](ClO 4 ) 2 (CH 3 OH) 2 , being consistent with the results of the elemental analysis and magnetic measurements (see below). From the Fe-N bond lengths (Table 2), the state is suggested to be LS at 100 K. The molecular structure ( Figure 1d) displays a relatively linear N(py)-Fe-N(py) axis (176.62 (19) • ), as usually found in the LS molecules of this family.…”
Section: Crystal Structuressupporting
confidence: 69%
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“…There is a unique crystallographically-independent molecule. The crystal involves two molar methanol molecules; namely, the composition formula is [Fe(CH 3 S-pybox) 2 ](ClO 4 ) 2 (CH 3 OH) 2 , being consistent with the results of the elemental analysis and magnetic measurements (see below). From the Fe-N bond lengths (Table 2), the state is suggested to be LS at 100 K. The molecular structure ( Figure 1d) displays a relatively linear N(py)-Fe-N(py) axis (176.62 (19) • ), as usually found in the LS molecules of this family.…”
Section: Crystal Structuressupporting
confidence: 69%
“…From the N-Fe-N bond angles summarized in Table 3, we can calculate the Σ value [37] for estimation of distortion degree (Table 4), according to Equation (2). An ideal octahedron (Oh) possesses Σ = 0 • .…”
Section: Coordination Structure Effectmentioning
confidence: 99%
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“…Spin instability in an isolated complex is well understood already within ligand field theory5 and the collective behaviour of spin‐active molecules can be parameterized with Ising‐like models6 and a generic phase diagram is provided by Landau theory 7…”
mentioning
confidence: 99%