1997
DOI: 10.1002/(sici)1099-1395(199709)10:9<647::aid-poc927>3.0.co;2-0
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Solvatochromism of dyes. Part III. Solvatochromism of merocyanines in some binary mixtures of solvents.SA-SAB-SB, a new model of solvatochromism
Abstract: A quantitative model of solvatochromism in a binary solvent system is presented. Although it is derived for merocyanine and betaine dyes, it explains a majority of known examples of solvatochromism in binary solvents. The model provides an estimation of equilibrium constants between particular types of solvates present therein. UV-VIS absorption spectra of solvated species can be simulated. They perfectly fit the experimental data. The model proposed describes the internal solvent picture from the solute point…
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Cited by 12 publications
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