Solvation models in the reaction between phenacyl bromide and 2-mercaptobenzimidazole

Kavitha, B.; Manikyamba, P.

doi:10.1080/17415991003664755

Cited by 1 publication

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“…The near studies agreement by means of the effect of nucleophile, lying on the rate of reaction of benzyl bromide through cyclic amine in aqueous ethanol solvent mixtures. Many powerful tools are provides quantum chemistry which facilitate us in evaluate electron densities at different atoms of a molecule [6][7][8][9][10] , in predicting the reaction site, in explaining the order of reactivity of closely related reagents towards a given substrate, in predicting the transition state structure, etc. In the present communication the authors report their observations on the conductance behaviour of cyclicamines in aqueous mixtures of ethanol.…”

Section: Introductionmentioning

confidence: 99%

Conductance Study of Benzyl Bromide Reaction with Cyclicamines in Aqueous-Ethanol Medium

Radhika¹,

2018

IJET

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Nucleophilic substitution reaction of benzyl bromide and cyclicamines in ethanol aqueous intermediate reactivity can suggest that the nucleophile increases through their pKa values. A linear correlation exists between computed values of the dipole moment, rate and electronegativity of the nucelophiles. The two reactants suggest that frontier molecular orbital interactions ion-solvation and correlation of time with the HOMO-LUMO breach of that the reaction. But it is not orbital controlled as well as forbidden by the electrostatic interactions along with mixed solvent composition between the reactants. The influence on the solvation of ions before reaction has been discuss with facilitate by R-factor. Thermodynamic properties are evaluate and report. The consequences of the learning to be interpreted in terms of ion-solvent exchanges and solvent properties comparing with electrostatic interaction between the reactants.

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Section: Introductionmentioning

confidence: 99%

Conductance Study of Benzyl Bromide Reaction with Cyclicamines in Aqueous-Ethanol Medium

Radhika¹,

2018

IJET

View full text Add to dashboard Cite

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Solvation models in the reaction between phenacyl bromide and 2-mercaptobenzimidazole

Cited by 1 publication

References 9 publications

Conductance Study of Benzyl Bromide Reaction with Cyclicamines in Aqueous-Ethanol Medium

Conductance Study of Benzyl Bromide Reaction with Cyclicamines in Aqueous-Ethanol Medium

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