We explore ways to actively control near--field radiative heat transfer between two surfaces that relies on electrical tuning of phonon modes of ferroelectric materials. Ferroelectrics are widely used for tunable electrical devices such as capacitors and memory devices; however, their tunable propertieshave not yet been examined for heat transfer applications. We show via simulations that radiative heat transfer between two ferroelectric materials can be enhanced by over two orders of magnitude over the blackbody limit in the near field, and can be tuned as much as 16.5% by modulating the coupling between surface phonon polariton modes at the two surfaces via varying external electric fields. We then discuss how to maximize the modulation contrast for tunable thermal devices using the studied mechanism.Keywords: Ferroelectrics, Near--field Radiation, Tunable Heat Transfer, Energy Transport, Surface
Phonon PolaritonsIt has already been demonstrated both experimentally and theoretically that thermal emission and radiative heat exchange between hot and cold surfaces is modified dramatically when the surfaces are brought into a close proximity [1 -11]. At separation distances smaller than the dominant wavelength of thermal radiation, the radiative heat flux has been demonstrated to be orders of magnitude higher than the blackbody limit predicted by the Planck and the Stefan--Boltzmann laws [3 --9]. One major reason for such enhancement is that photons can couple resonantly with optical phonons in polar materials at the material surface to form surface phonon polariton (SPP) waves [3 -11], which † To whom correspondence should be addressed gchen2@mit.edu 2 exponentially decay from the surface but can tunnel through the vacuum gap between hot and cold surfaces when the gap size is small [3 --11]. Several calculations and experiments have shown that near--field radiative heat flux can be controlled by modifying the geometries of thermal emitters and absorbers [13 --19] as well as by using materials with externally variable optical properties, such as vanadium dioxide that undergoes a metal--insulator transition [20,22,23], semiconductors with different levels of doping [25,26], modulation of graphene optical properties via electrostatic gating [27,28], dynamic magnetoelectric coupling in metamaterials [29], and modulation of intersubband transition rates in a quantum cascade laser [30]. In this paper, we investigate an approach to actively control radiative heat flux via applying external electric field that causes the softening (i.e. decrease in frequency) and hardening (i.e. increase in frequency) of transverse optical (TO) phonon mode in ferroelectric materials [32, 34 --38].Tunability of the TO phonon mode in perovskite--structure ferroelectric materials stems from the material structure instability [31, 32, 34 --38]. One unique property of ferroelectrics is that its static dielectric constant can be modulated by external dc electric field and temperature by inducing crystal structure changes within the ma...