1996
DOI: 10.1002/(sici)1099-1395(199606)9:6<403::aid-poc799>3.0.co;2-d
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Solute-solvent and solvent-solvent interactions in binary solvent mixtures. 2. Effect of temperature on theET(30) polarity parameter of dipolar hydrogen bond acceptor-hydrogen bond donor mixtures
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1996
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Cited by 90 publications
(39 citation statements)
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“…In fact, in this case, the slight difference between E N T 12 and E N T for methanol has formerly led us to consider this solvent mixture as nonsynergetic and therefore described by Scheme . The present perspective is in line with the tendency reported by Bosch and Rosés et al for MeCN−cosolvent mixtures. ,, …”
Section: Resultssupporting
confidence: 94%
“…In fact, in this case, the slight difference between E N T 12 and E N T for methanol has formerly led us to consider this solvent mixture as nonsynergetic and therefore described by Scheme . The present perspective is in line with the tendency reported by Bosch and Rosés et al for MeCN−cosolvent mixtures. ,, …”
Section: Resultssupporting
confidence: 94%
“…In the present work we used a solvation model introduced by Rosés et al; we give its essentials below; more details are reported elsewhere. − The solvent-exchange equilibria in the solvation layer of the probe are given by eqs and : where all concentrations are given on the mole fraction scale. The term m is the number of solvent molecules in the solvation layer that affects the probe’s solvatochromic response, usually m ≤ 2.…”
Section: Results
and Discussionmentioning
confidence: 99%
“…The Rosés and Bosch model for preferential solvation is cast in terms of solvent exchange equilibria as in Equations (2) and (3) [16,17,18,19,20,21,22,23]. However, the model is typically applied to ground state species.…”
Section: Resultsmentioning
confidence: 99%
